A porous 3D heterometal-organic framework containing both lanthanide and high-spin Fe(ii) ions

作者：Bin Zhao, Xiao-Yan Chen, Zhi Chen, Wei Shi, Peng Cheng, Shi‐Ping Yan, Dai‐Zheng Liao · 发表于：Chemical Communications · 年份：2009 · DOI：10.1039/b821496d · 被引用次数：147 · 研究领域：Metal-Organic Frameworks: Synthesis and Applications、Lanthanide and Transition Metal Complexes、Magnetism in coordination complexes

The first porous 3D [Ln-Fe] heterometal-organic frameworks incorporating high-spin Fe(ii) ions were structurally characterized with fascinating 1D channels and higher thermal stability: the robust frameworks still keep intact on removing free H(2)O or adsorbing C(2)H(5)OH, and the luminescence of [Eu-Fe] complex displays selective detection of Mg(2+).