The use of multiple quantum transitions for relaxation studies in coupled spin systems

作者：Alexander Wokaun, Richard R. Ernst · 发表于：Molecular Physics · 年份：1978 · DOI：10.1080/00268977800101601 · 被引用次数：160 · 研究领域：NMR spectroscopy and applications、Advanced NMR Techniques and Applications、Spectroscopy and Quantum Chemical Studies

The utility of multiple quantum transitions is discussed with regard to the elucidation of relaxation mechanisms in coupled spin systems. The information contained in the decay rates of multiple quantum coherence is analysed in terms of the Redfield formalism, and experimental schemes suitable for their measurement are presented. As an illustration, external paramagnetic relaxation in a two-spin system is investigated, based on measured multiple and single quantum relaxation rates.