A Cubic (3,4)‐Connected Net with Large Cavities in Solvated [Cu3(tpt)4](ClO4)3 (tpt = 2,4,6‐Tri(4‐pyridyl)‐1,3,5‐triazine)
作者：Brendan F. Abrahams, Stuart R. Batten, Hasan Hamit, Bernard F. Hoskins, Richard Robson · 发表于：Angewandte Chemie International Edition in English · 年份：1996 · DOI：10.1002/anie.199616901 · 被引用次数：217 · 研究领域：Metal-Organic Frameworks: Synthesis and Applications、Supramolecular Chemistry and Complexes、Luminescence and Fluorescent Materials
Two independent and identical interpenetrating three-dimensional networks of a highly symmetrical type in which tpt ligands act as trigonal building blocks and CuI ions as tetrahedral 4-connecting units are contained in cubic crystals of the title compounds. Tpt units appear in centrosymmetrically related pairs within which triazine rings make close ππ contacts.