A Comparison of Particle-Particle, Particle-Mesh and Ewald Methods for Calculating Electrostatic Interactions in Periodic Molecular Systems

作者：Brock A. Luty, Malcolm E. Davis, Ilario G. Tironi, Wilfred F. van Gunsteren · 发表于：Molecular Simulation · 年份：1994 · DOI：10.1080/08927029408022004 · 被引用次数：235 · 研究领域：Advanced Chemical Physics Studies、Ion-surface interactions and analysis、Chemical and Physical Properties of Materials

We compare the Particle-Particle Particle-Mesh (PPPM) and Ewald methods for calculating electrostatic interactions in periodic molecular systems. A brief comparison of the theories shows that the methods are very similar differing mainly in the technique which is used to perform the “k-space” or mesh calculation. Because the PPPM utilizes the highly efficient numerical Fast Fourier Transform (FFT) method it requires significantly less computational effort than the Ewald method and scales almost linearly with system size.