Tailoring Microporosity in Covalent Organic Frameworks

作者：R. William Tilford, Sam J. Mugavero, Perry J. Pellechia, John J. Lavigne · 发表于：Advanced Materials · 年份：2008 · DOI：10.1002/adma.200800030 · 被引用次数：455 · 研究领域：Covalent Organic Framework Applications、Metal-Organic Frameworks: Synthesis and Applications、Advanced Photocatalysis Techniques

The microporosity of covalent organic frameworks (COFs) is tailored using a facile synthetic approach that introduces alkyl functionalities into the pore and generates networks with pore diameters between 1-2 nm. The added substituents significantly alter the host-guest properties of the resulting materials.