Pd/Cu‐Cocatalyzed Aerobic Oxidative Carbonylative Homocoupling of Arylboronic Acids and CO: A Highly Selective Approach to Diaryl Ketones

作者：Long Ren, Ning Jiao · 发表于：Chemistry - An Asian Journal · 年份：2014 · DOI：10.1002/asia.201402326 · 被引用次数：27 · 研究领域：Catalytic C–H Functionalization Methods、Catalytic Cross-Coupling Reactions、Asymmetric Hydrogenation and Catalysis

A highly selective Pd/Cu-cocatalyzed aerobic oxidative carbonylative homocoupling of arylboronic acids has been developed. This method employs a simple catalytic system, readily available boronic acids as the substrates, molecular oxygen as the oxidant, and 1 atm of CO/O2 , which makes this method practical for further applications.