Microscopic spin Hamiltonian of a Cr8 antiferromagnetic ring from inelastic neutron scattering

作者：Stefano Carretta, Joris van Slageren, T. Guidi, Emilia Liviotti, C. Mondelli, Donella Rovai, Andrea Cornia, Angela L. Dearden, F. Carsughi, M. Affronte, C. D. Frost, Richard E. P. Winpenny, Dante Gatteschi, G. Amoretti, R. Caciuffo · 发表于：Physical review. B, Condensed matter · 年份：2003 · DOI：10.1103/physrevb.67.094405 · 被引用次数：131 · 研究领域：Magnetism in coordination complexes、Lanthanide and Transition Metal Complexes、Organic and Molecular Conductors Research

Exchange integrals and single-ion anisotropy parameters of a ring-shaped molecular cluster, comprising eight chromium(III) ions $(s=3/2)$ were determined by inelastic neutron scattering. Effects due to the mixing of different spin multiplets have been considered. Such effects proved to be important to correctly reproduce the relative intensity of magnetic excitations in the neutron spectra. Evidence of decreasing lifetimes with increasing energy of excited spin states was found. The microscopic picture emerging from neutron spectroscopy was confirmed by the temperature dependence of the heat capacity.