Synthesis, structural characterisation and luminescence studies of the first alkynyl stabilised platinum–cadmium complexes

作者：J.P.H. Charmant, Julio Goméz, A. Guy. Orpen, Larry R. Falvello, J. Forniés, Adoracion Rueda, Julio Goméz, Elena Lalinde, Maria Teresa Moreno · 发表于：Chemical Communications · 年份：1999 · DOI：10.1039/a906394c · 被引用次数：37 · 研究领域：Organometallic Complex Synthesis and Catalysis、Metal complexes synthesis and properties、Organic Light-Emitting Diodes Research

The simple 1∶2 adduct (NBu4)2[{Pt(µ-κCα:η2- CCPh)4}(CdCl2)2] 2 containing unusual η2-alkyne Cd interactions, as well as the unexpected tetranuclear dimer (NBu4)2[{Pt(µ-κCαCα-CCPh)4}2(CdCl)2] 1 stabilised by alkynyl bridging ligands and platinum–cadmium bonding interactions, have been characterised by X-ray crystallography and their luminescence properties have been also investigated.