pH-Dependent Assembly of Keggin-Based Supramolecular Architecture

作者：Pei‐Qing Zheng, Yan‐Ping Ren, La‐Sheng Long, Rong‐Bin Huang, Lan‐Sun Zheng · 发表于：Inorganic Chemistry · 年份：2005 · DOI：10.1021/ic048708s · 被引用次数：264 · 研究领域：Metal-Organic Frameworks: Synthesis and Applications、Polyoxometalates: Synthesis and Applications、Supramolecular Self-Assembly in Materials

Three Keggin-based supramolecular architectures were synthesized on the basis of same molecular building units, showing that the pH value of the reaction plays a crucial role in controlling the topological structures of the supramolecular architectures.