Hydrothermal Synthesis and Characterization of a Novel Sinusoidal Layer Structure Constructed From Polyoxometalates and Coordination Complex Fragments

作者：Xiao‐Bing Cui, Ji‐Qing Xu, Yong Li, Yinghua Sun, Guo‐Yu Yang · 发表于：European Journal of Inorganic Chemistry · 年份：2004 · DOI：10.1002/ejic.200300593 · 被引用次数：77 · 研究领域：Polyoxometalates: Synthesis and Applications、Metal-Organic Frameworks: Synthesis and Applications、Advanced Nanomaterials in Catalysis

Abstract A novel polyoxometalate compound, [As 8 V 14 O 42 (SO 4 )][Ni(en) 2 ] 3 ·4.5H 2 O ( 1 ), has been synthesized by a hydrothermal method and characterized by X‐ray crystallography, showing that the compound 1 is the first example of a sinusoidal layer structure constructed from polyoxometalates and coordination complex fragments. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)