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Effective, transition metal free and selective C–F activation under mild conditions

作者:Xianqiang Kong, Huizi Zhang, Yunqing Xiao, Changsheng Cao, Yanhui Shi, Guangsheng Pang · 发表于:RSC Advances · 年份:2014 · DOI:10.1039/c4ra13753a · 被引用次数:36 · 研究领域:Fluorine in Organic Chemistry、Catalytic C–H Functionalization Methods、Cyclopropane Reaction Mechanisms

A simple and effective aromatic nucleophilic monosubstitution reaction for the synthesis of aromatic amines via selective C–F bond cleavage of various fluoroarenes with primary and secondary aromatic amines is demonstrated.