Synthesis, crystal structure and some derivatives of the chlorotris(tetramethylphospholyl)uranium

作者：Philippe Gradoz, Christophe Boisson, Denise Baudry, M. Lance, M. Nierlich, Julien Vigner, M. Ephritikhine · 发表于：Journal of the Chemical Society Chemical Communications · 年份：1992 · DOI：10.1039/c39920001720 · 被引用次数：37 · 研究领域：Radioactive element chemistry and processing、Organometallic Complex Synthesis and Catalysis、Coordination Chemistry and Organometallics

Reaction of UCl4 with the potassium salt of the tetramethylphospholyl anion afforded the title compound, which has been transformed into the derivatives [U(η-C4Me4P)3X](X = H, Me, OPri); the trigonal crystal structure revealed that the three phospholyl ligands are pentahapto bonded to the uranium.