Synthesis and characterisation of the persistent radical [BCl2(bipy)]˙

作者：Stephen M. Mansell, Christopher J. Adams, George Bramham, M.F. Haddow, Wolfgang Kaim, Nicholas C. Norman, John E. McGrady, Christopher A. Russell, S.J. Udeen · 发表于：Chemical Communications · 年份：2010 · DOI：10.1039/c0cc00187b · 被引用次数：35 · 研究领域：Magnetism in coordination complexes、Photochemistry and Electron Transfer Studies、Synthesis and Properties of Aromatic Compounds

The persistent radical, [BCl(2)(bipy)](*) (bipy = 2,2'-bipyridyl), has been prepared and characterised by X-ray crystallography, ESR and DFT calculations. The structure is compared with that of the cation, [BCl(2)(bipy)](+).