Uncompensated Resistance. 1. The Effect of Cell Geometry

作者：Jan C. Myland, Keith B. Oldham · 发表于：Analytical Chemistry · 年份：2000 · DOI：10.1021/ac0001535 · 被引用次数：83 · 研究领域：Electrochemical Analysis and Applications、Analytical Chemistry and Sensors、Conducting polymers and applications

The meaning and significance of uncompensated resistance are carefully explained. Many factors influence the uncompensated resistance and several of these are explored in this article, using idealized models of an electrochemical cell. Among the factors whose roles have been elucidated are the shape and size of the cell, the location of the reference electrode, the shape of the working electrode, and the size and position of the counter electrode. Worthwhile compensation is shown to be impossible with microelectrodes.