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New Gas-Phase Cascade Reactions of Stabilized Phosphorus Ylides Leading to Ring-Fused Indoles and to Quinolines

作者:R. A. Aitken, Lorna Murray · 发表于:The Journal of Organic Chemistry · 年份:2008 · DOI:10.1021/jo801716z · 被引用次数:29 · 研究领域:Cyclopropane Reaction Mechanisms、Phosphorus compounds and reactions、Synthesis and Catalytic Reactions

Gas-phase cyclization processes of stabilized phosphorus ylides bearing a suitably substituted 2-aminophenyl group lead efficiently either to 3-substituted quinolines or benzo[c]carbazole and heterocyclic-fused analogues depending on the substituents present.