Cylindrical Micelles of Controlled Length with a π-Conjugated Polythiophene Core via Crystallization-Driven Self-Assembly

作者：Sanjib K. Patra, Rumman Ahmed, George R. Whittell, David J. Lunn, Emma L. Dunphy, Mitchell A. Winnik, Ian Manners · 发表于：Journal of the American Chemical Society · 年份：2011 · DOI：10.1021/ja202408w · 被引用次数：268 · 研究领域：Advanced Polymer Synthesis and Characterization、Polymer composites and self-healing、Conducting polymers and applications

Solution self-assembly of the regioregular polythiophene-based block copolymer poly(3-hexylthiophene)-b-poly(dimethylsiloxane) yields cylindrical micelles with a crystalline P3HT core. Monodisperse nanocylinders of controlled length have been prepared via crystallization-driven self-assembly using seed micelles as initiators.