A Simple Catalytic Method for the Conversion of Aryl Bromides to Arylamines

作者：Anil S. Guram, Roger A. Rennels, Stephen L. Buchwald · 发表于：Angewandte Chemie International Edition in English · 年份：1995 · DOI：10.1002/anie.199513481 · 被引用次数：1063 · 研究领域：Catalytic Cross-Coupling Reactions、Catalytic C–H Functionalization Methods、Chemical Synthesis and Reactions

A facile Pd-catalyzed method for the preparation of a wide variety of aryl amines from aryl bromides and amines has been developed [Eq. (a)]. Noteworthy features of this method include the experimental simplicity, the tin/boron-free conditions, and the broad spectrum of potential substrates.