A Facile Pd(0)-Catalyzed Regio- and Stereoselective Diamination of Conjugated Dienes and Trienes

作者：Haifeng Du, Baoguo Zhao, Yian Shi · 发表于：Journal of the American Chemical Society · 年份：2007 · DOI：10.1021/ja0680562 · 被引用次数：234 · 研究领域：Catalytic C–H Functionalization Methods、Synthesis and Catalytic Reactions、Asymmetric Hydrogenation and Catalysis

This paper describes a novel diamination process using di- t -butyldiaziridinone as the nitrogen source and Pd(PPh 3 ) 4 as catalyst. A wide variety of conjugated dienes and trienes can be effectively diaminated in good yields with high regio- and stereoselectivities in short reaction time.