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The effect of doping transition metal oxides on copper manganese oxides for the catalytic oxidation of CO

作者:Lina Cai, Zhen-Hao Hu, Peter Branton, Wen‐Cui Li · 发表于:CHINESE JOURNAL OF CATALYSIS (CHINESE VERSION) · 年份:2014 · DOI:10.1016/s1872-2067(12)60699-8 · 被引用次数:64 · 研究领域:Catalytic Processes in Materials Science、Catalysis and Oxidation Reactions、Copper-based nanomaterials and applications

A series of copper manganese oxides doped with transition metal oxides were prepared by co-precipitation using copper acetate and manganese acetate as precursors, ammonium bicarbonate as precipitant, and metal nitrates as dopants. The catalysts were characterized by N2 adsorption-desorption, X-ray powder diffraction, temperature-programmed reduction, and in situ diffuse reflectance infrared Fourier transform spectroscopy. The results showed that doping transition metal oxides into copper manganese oxides can modify the CO adsorption ability of the catalyst and thus affect the catalytic oxidation of CO.