Selective Nickel- and Manganese-Catalyzed Decarboxylative Cross Coupling of Some α,β-Unsaturated Carboxylic Acids with Cyclic Ethers

作者：Jiaxiang Zhang, Yanjing Wang, Wei Zhang, Nai‐Xing Wang, Cui‐Bing Bai, Yalan Xing, Yihe Li, Jia‐Long Wen · 发表于：Scientific Reports · 年份：2014 · DOI：10.1038/srep07446 · 被引用次数：41 · 研究领域：Catalytic C–H Functionalization Methods、Catalytic Cross-Coupling Reactions、Cyclopropane Reaction Mechanisms

A nickel- and manganese-catalyzed decarboxylative cross coupling of α, β-unsaturated carboxylic acids with cyclic ethers such as tetrahydrofuran and 1, 4-dioxane was developed. Oxyalkylation was achieved when nickel acetate was used as catalyst, while manganese acetate promoted the reaction of alkenylation.