A Novel Pillar-Layered Organic−Inorganic Hybrid Based on Lanthanide Polymer and Polyomolybdate Clusters:  New Opportunity toward the Design and Synthesis of Porous Framework

作者：Jian Lü, Enhong Shen, Yangguang Li, Dong‐Rong Xiao, Enbo Wang, Lin Xu · 发表于：Crystal Growth & Design · 年份：2004 · DOI：10.1021/cg049732j · 被引用次数：143 · 研究领域：Metal-Organic Frameworks: Synthesis and Applications、Polyoxometalates: Synthesis and Applications、Nanocluster Synthesis and Applications

An unprecedented microporous lanthanum polymolybdate, [{La(H 2 O) 5 (dipic)}{La(H 2 O)(dipic)}] 2 {Mo 8 O 26 }·10H 2 O (H 2 dipic = pyridine-2,6-dicarboxylic acid) 1, which is constructed from lanthanum−organic coordination polymer sheets pillared by individual octamolybdate clusters, is reported.