Ferromagnetism in Fe-doped ZnO nanocrystals: Experiment and theory

作者：Debjani Karmakar, Sanjay Kumar Mandal, Ramakant Mahadeo Kadam, P. L. Paulose, A. K. Rajarajan, Tapan Kumar Nath, A. K. Das, Indra Dasgupta, Gour Prasad Das · 发表于：Physical Review B · 年份：2007 · DOI：10.1103/physrevb.75.144404 · 被引用次数：420 · 研究领域：ZnO doping and properties、Copper-based nanomaterials and applications、Magnetic and transport properties of perovskites and related materials

Fe-doped ZnO nanocrystals are successfully synthesized and structurally characterized by using x-ray diffraction and transmission electron microscopy. Magnetization measurements on the same system reveal a ferromagnetic to paramagnetic transition temperature above $450\phantom{\rule{0.3em}{0ex}}\mathrm{K}$ with a low-temperature transition from the ferromagnetic to the spin-glass state due to canting of the disordered surface spins in the nanoparticle system. Local magnetic probes like electron paramagnetic resonance and M\"ossbauer spectroscopy indicate the presence of Fe in both valence states ${\mathrm{Fe}}^{2+}$ and ${\mathrm{Fe}}^{3+}$. We argue that the presence of ${\mathrm{Fe}}^{3+}$ is due to possible hole doping in the system by cation (Zn) vacancies. In a subsequent ab initio electronic structure calculation, the effects of defects (e.g., O and Zn vacancies) on the nature and origin of ferromagnetism are investigated for the Fe-doped ZnO system. Electronic structure calculations suggest hole doping (Zn vacancy) to be more effective to stabilize ferromagnetism in Fe-doped ZnO and our results are consistent with the experimental signature of hole doping in ferromagnetic Fe-doped ZnO samples.