Template‐Mediated Self Assembly of Six‐ and Eight‐Membered Iron Coronates

作者：Rolf W. Saalfrank, Ingo Bernt, Eveline Uller, Frank Hampel · 发表于：Angewandte Chemie International Edition in English · 年份：1997 · DOI：10.1002/anie.199724821 · 被引用次数：273 · 研究领域：Magnetism in coordination complexes、Supramolecular Chemistry and Complexes、Lanthanide and Transition Metal Complexes

The type of bait determines the prey: in a pond with triethanolamine ligands and iron(III) ions, six- (1) or eight-membered (2) iron coronates can be captured, depending upon whether sodium or cesium ions are used as the bait. This finding is especially interesting in connection with a possible combinatiorial approach in supramolecular chemistry.