Improved Hydrogen Storage in the Metal‐Organic Framework Cu3(BTC)2

作者：Piotr Krawiec, Markus Krämer, Michal Sabo, R. Kunschke, Heidrun Fröde, Stefan Kaskel · 发表于：Advanced Engineering Materials · 年份：2006 · DOI：10.1002/adem.200500223 · 被引用次数：195 · 研究领域：Metal-Organic Frameworks: Synthesis and Applications、Hydrogen Storage and Materials、Crystallography and molecular interactions

A new pressure‐free synthesis method was developed producing the porous material Cu3(BTC)2 (BTC = benzene tricarboxylate) with a very high micropore volume up to 0.62 cm3g–1. The compound is a promising nanoporous solid for adsorptive hydrogen storage under cryogenic conditions with a capacity of 2.18 wt% which is higher than that of IRMOFs and other coordination polymers.