Vibrational spectra of water molecules at quartz/water interfaces

作者：Quan Du, E. Freysz, Y. R. Shen · 发表于：Physical Review Letters · 年份：1994 · DOI：10.1103/physrevlett.72.238 · 被引用次数：579 · 研究领域：Spectroscopy and Quantum Chemical Studies、Methane Hydrates and Related Phenomena、Spectroscopy and Laser Applications

Optical sum-frequency generation was used to study OH stretch vibrations of water molecules at fused quartz-water interfaces. The results indicate that orientations and bond ordering of interfacial water molecules are strongly affected by electrostatic interaction and hydrogen bonding of the molecules with the quartz surface.