Dual Redox Responsive Assemblies Formed from Diselenide Block Copolymers

作者：Ning Ma, Ying Li, Huaping Xu, Zhiqiang Wang, Xi Zhang · 发表于：Journal of the American Chemical Society · 年份：2009 · DOI：10.1021/ja908124g · 被引用次数：720 · 研究领域：Advanced Polymer Synthesis and Characterization、Polyoxometalates: Synthesis and Applications、Chemical Synthesis and Reactions

A block copolymer with diselenide bonds in the polymer backbone was reported. This block copolymer was capable of forming micellar aggregates that were responsive to redox stimuli. Compared with other redox responsive aggregates, this type of diselenide-containing block copolymer aggregates could be responsive to both oxidants and reductants even in a solution with a very low concentration under mild conditions.