Synthesis and Crystal Structures of Octahedral Metal Complexes containing the New Dianion [PhP(Se,O)Se‐Se(O,Se)PPh]2−

作者：Weifeng Shi, Le Zhang, M. Shafaei-Fallah, A. Rothenberger · 发表于：Zeitschrift für anorganische und allgemeine Chemie · 年份：2007 · DOI：10.1002/zaac.200600297 · 被引用次数：13 · 研究领域：Crystal Structures and Properties、Crystal structures of chemical compounds、Organometallic Compounds Synthesis and Characterization

Abstract The synthesis and structures of three new compounds are reported. [Mg2{PhP(Se,O)Se‐Se(O,Se)PPh}2(thf)7(H2O)3] (1), [Mg{PhP(Se,O)Se‐Se(O,Se)PPh}(thf)3(H2O)] (2), and [Mn{PhP(Se,O)Se‐Se(O,Se)PPh}(thf)3(H2O)] (3) were prepared by treatment of Woollins' reagent [PhP(Se)(μ‐Se)]2 with the corresponding hydrated metal acetates.