Hydrolysis of Iron(III)…Chaotic Olation Versus Nucleation

作者：William F. Schneider · 发表于：Comments on Inorganic Chemistry · 年份：1984 · DOI：10.1080/02603598408078138 · 被引用次数：88 · 研究领域：Mine drainage and remediation techniques、Iron oxide chemistry and applications、Minerals Flotation and Separation Techniques

At moderate temperatures, a variety of sols, gels, amorphous or crystalline precipitates emerge from hydrolysis of iron(III) in aqueous solution. The product distribution reflects the interplay of fast proton transfer, olation and aggregation reactions. Polynuclear oxohydroxocomplexes with well-defined structures are formed under favorable circumstances in homogeneous solution. Polynuclear species with β-FeO(OH) structures have been identified in chloride solutions.