Organic Synthesis by Catalysis with Ion-Exchange Resins

作者：Georges Gelbard · 发表于：Industrial & Engineering Chemistry Research · 年份：2005 · DOI：10.1021/ie0580405 · 被引用次数：197 · 研究领域：Chemical Synthesis and Reactions、Chemical Synthesis and Analysis、Analytical Chemistry and Chromatography

This review is intended to give a wide scope on the uses of ion-exchange resins as catalysts or catalyst precursors in organic synthesis, for the preparation of fine or intermediate chemicals. Twelve families of reaction have been covered and presented according to the molecules to be synthesized, regardless of the anionic or cationic nature of the resins; thus, ∼300 references have been selected from January 1980. In acid-catalyzed reactions, the contribution of both Lewis acidity and Brönsted acidity are mentioned, and, when available, some aspects related to the stability or the recycling of the catalysts are reported. In base-catalyzed reactions, the importance of the thermal stability of anionic resins has been underlined. A table that is included as an appendix provides some data on the resins quoted here.