The structures and magnetic properties of complexes containing 3d- and 4f-metals

作者：Richard E. P. Winpenny · 发表于：Chemical Society Reviews · 年份：1998 · DOI：10.1039/a827447z · 被引用次数：456 · 研究领域：Magnetism in coordination complexes、Organometallic Complex Synthesis and Catalysis、Lanthanide and Transition Metal Complexes

Heterometallic complexes containing 3d-/4f-metals have been made with a variety of ligands including Schiff-bases, pyridonates and amino-alcohols. The majority of species with Schiff-base ligands are trinuclear with Cu2Ln cores, and with other ligands larger oligomers are found, ranging as large as Cu12La8 and Cu12Ln6 clusters (Ln = Y, Nd, Sm or Gd). The magnetic properties displayed by these polynuclear species are discussed, and the magnetic coupling between CuII and GdIII is always found to be ferromagnetic.