Metal–Organic Nanoporous Structures with Anisotropic Photoluminescence and Magnetic Properties and Their Use as Sensors

作者：Bogdan V. Harbuzaru, Avelino Corma, Fernando Rey, Pedro Atienzar, Jose Luis Jordá, Hermenegildo Garcı́a, Duarte Ananias, Luís D. Carlos, João Rocha · 发表于：Angewandte Chemie International Edition · 年份：2008 · DOI：10.1002/anie.200704702 · 被引用次数：402 · 研究领域：Lanthanide and Transition Metal Complexes、Metal-Organic Frameworks: Synthesis and Applications、Magnetism in coordination complexes

Shining bright: Porous metal–organic framework materials are important owing to their potential applications as sensors. A new family of nanoporous, multifunctional rare-earth metal–organic materials displays emission quantum yields and efficiencies that are the highest reported for solid-state Eu3+ compounds with organic ligands and magnetic properties. The picture shows [Gd,Eu]- and [Tb]-containing materials under UV light and interacting with a magnet.