Pillared Porphyrin Homologous Series: Intergrowth in Metal−Organic Frameworks

作者：Eun‐Young Choi, P.M. Barron, Richard W. Novotny, Hyun-Tak Son, Chunhua Hu, Wonyoung Choe · 发表于：Inorganic Chemistry · 年份：2008 · DOI：10.1021/ic801677y · 被引用次数：186 · 研究领域：Metal-Organic Frameworks: Synthesis and Applications、Supramolecular Chemistry and Complexes、Porphyrin and Phthalocyanine Chemistry

We report three new porphyrin-based, pillared paddle-wheel homologous series: porphyrin paddle-wheel frameworks PPF-3, -4, and -5. These compounds are assembled from free base or palladium tetrakis(4-carboxyphenyl)porphine, M(NO(3))(2) (M = Co and Zn), and 4,4'-bipyridine via solvothermal reactions. The resulting solids exhibit 3D metal-organic frameworks, where 2D layers are pillared by bipyridine with three different packing arrangements.