Infrared Spectra and Molecular Structures of SiH3F, SiH3Cl, and SiH3Br

作者：Carolyn Newman, J. Kenneth O'Loane, Santiago R. Polo, M. Kent Wilson · 发表于：The Journal of Chemical Physics · 年份：1956 · DOI：10.1063/1.1743133 · 被引用次数：98 · 研究领域：Atomic and Molecular Physics、Advanced Chemical Physics Studies、Glass properties and applications

The structure of the e-type fundamentals of SiH3F, SiH3Cl, and SiH3Br has been resolved and analyzed. The values of the small amount of inertia thus obtained has been combined with microwave measurements to yield the dimensions of the SiH3 group in these molecules. It is shown that the differences in the structure of the SiH3 group are probably within experimental error. Several revisions have been made in the vibrational assignments for SiH3F and SiH3Cl.