Cascade Catalysis for the Homogeneous Hydrogenation of CO 2 to Methanol

作者：Chelsea A. Huff, Melanie Sarah Sanford · 发表于：Journal of the American Chemical Society · 年份：2011 · DOI：10.1021/ja208760j · 被引用次数：584 · 研究领域：Carbon dioxide utilization in catalysis、Asymmetric Hydrogenation and Catalysis、CO2 Reduction Techniques and Catalysts

This communication demonstrates the homogeneous hydrogenation of CO(2) to CH(3)OH via cascade catalysis. Three different homogeneous catalysts, (PMe(3))(4)Ru(Cl)(OAc), Sc(OTf)(3), and (PNN)Ru(CO)(H), operate in sequence to promote this transformation.