Discrimination of product isomers in the photodissociation of propyne and allene at 193 nm

作者：Weizhong Sun, Keiichi Yokoyama, Jason C. Robinson, Arthur G. Suits, Daniel M. Neumark · 发表于：The Journal of Chemical Physics · 年份：1999 · DOI：10.1063/1.478318 · 被引用次数：62 · 研究领域：Advanced Chemical Physics Studies、Catalysis and Oxidation Reactions、Mass Spectrometry Techniques and Applications

The photodissociation dynamics of propyne and allene are investigated in two molecular beam/photodissociation instruments, one using electron impact ionization and the other using tunable vacuum ultraviolet (VUV) light to photoionize the photoproducts. The primary dissociation channels for both reactants are C3H3+H and C3H2+H2. Measurement of the photoionization efficiency curves on the VUV instrument shows that the C3H3 product from propyne is the propynyl (CH3CC) radical, whereas the C3H3 product from allene is the propargyl (CH2CCH) radical. The dominant C3H2 product from both reactants is the propadienylidene (H2CCC) radical. We also observe a small amount of secondary C3H2 product from photodissociation of the C3H3 radicals in both cases.