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Semiquinone anion radicals of catechol(amine)s, catechol estrogens, and their metal ion complexes.

作者:Balaraman Kalyanaraman, Christopher C. Felix, Roger C. Sealy · 发表于:Environmental Health Perspectives · 年份:1985 · DOI:10.1289/ehp.8564185 · 被引用次数:161 · 研究领域:Free Radicals and Antioxidants、Electron Spin Resonance Studies、Antioxidant Activity and Oxidative Stress

The characterization and identification of semiquinone radicals from catechol(amine)s and catechol estrogens by electron spin resonance spectroscopy is addressed. The use of diamagnetic metal ions, especially Mg2+ and Zn2+ ions, to detect transient semiquinone radicals in biological systems and to monitor their reactions, is discussed. A brief account of the identification and reactions of quinones is also presented.