Selective Coupling of Non-Activated Olefins with Ethyl Cyanoacetate by Mn3+-Mediated Anodic Oxidation

作者：Ryushi Shundo, Ikuzo Nishiguchi, Yoshiharu MATSUBARA, Tsuneaki Hirashima · 发表于：Chemistry Letters · 年份：1990 · DOI：10.1246/cl.1990.2285 · 被引用次数：24 · 研究领域：Oxidative Organic Chemistry Reactions、Radical Photochemical Reactions、Catalytic C–H Functionalization Methods

Abstract Novel carbon-carbon bond formation of non-activated olefins with ethyl cyanoacetate has been developed by anodic oxidation using only a small amount of Mn(OAc)2·4H2O to give selectively either saturated or unsaturated coupling products depending upon the presence of a catalytic amount of Cu(OAc)2·H2O.