Rate of Electron Exchange between Cuprous and Cupric Ions in Hydrochloric Acid Solutions by Nuclear Magnetic Resonance

作者：Harden M. McConnell, Harry E. Weaver · 发表于：The Journal of Chemical Physics · 年份：1956 · DOI：10.1063/1.1742877 · 被引用次数：66 · 研究领域：Solid-state spectroscopy and crystallography、Advanced NMR Techniques and Applications、Chemical Synthesis and Characterization

A determination of the Cu63 nuclear resonance line width in concentrated hydrochloric acid solutions containing both cuprous and cupric chloride leads to an evaluation of the bimolecular rate constant k for the electron exchange process Cu+++Cu+→+Cu++Cu++.The experimentally determined value for k is k = 0.5×108 liter/mole-second.