Crystallographic Study of a Single Crystal to Single Crystal Photodimerization and Its Thermal Reverse Reaction
作者:Kathleen Novak, Volker Enkelmann, Gerhard Wegner, Kenneth B. Wagener · 发表于:Angewandte Chemie International Edition in English · 年份:1993 · DOI:10.1002/anie.199316141 · 被引用次数:130 · 研究领域:Crystallization and Solubility Studies、Catalysis and Oxidation Reactions、Various Chemistry Research Topics
Reversibility is the salient feature of the photochemical solid-state reaction of 1 to 2. Prerequisites, however, are first that the compound is irradiated into the long-wavelength flank of the absorption band of the chromophore (λ = 570 nm), and second that the product is not recrystallized before the thermal reverse reaction.