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Switchable and selective detection of Zn 2+ or Cd 2+ in living cells based on 3′-O-substituted arrangement of benzoxazole-derived fluorescent probes

作者:Yongqian Xu, Liangliang Xiao, Shiguo Sun, Zhichao Pei, Yuxin Pei, Yi Pang · 发表于:Chemical Communications · 年份:2014 · DOI:10.1039/c4cc02335h · 被引用次数:62 · 研究领域:Molecular Sensors and Ion Detection、Luminescence and Fluorescent Materials、Electrochemical Analysis and Applications

Two benzoxazole-derived ESIPT fluorescent sensors and show highly selective detection of Zn(2+) and Cd(2+), respectively, in aqueous solution and living cells. The selectivity switching from Zn(2+) to Cd(2+) is attributed to the different binding mode which is dependent on the 3'-O-substituted arrangement.