Solvent‐Induced Delamination of a Multifunctional Two Dimensional Coordination Polymer

作者：Almudena I. Gallego, Cristina Hermosa, Óscar Castillo, Isadora Berlanga, Carlos J. Gómez‐García, Eva Mateo‐Martí, José Ignacio Martínez, Fernando Flores, Cristina Gómez‐Navarro, Julio Gómez‐Herrero, Salomé Delgado, Félix Zamora · 发表于：Advanced Materials · 年份：2013 · DOI：10.1002/adma.201204676 · 被引用次数：162 · 研究领域：Metal-Organic Frameworks: Synthesis and Applications、Luminescence and Fluorescent Materials、Covalent Organic Framework Applications

A coordination polymer is fully exfoliated by solvent-assisted interaction only. The soft-delamination process results from the structure of the starting material, which shows a layered structure with weak layer-to-layer interactions and cavities with the ability to locate several solvents in an unselective way. These results represent a significant step forward towards the production of structurally designed one-molecule thick 2D materials with tailored physico-chemical properties.