Transformation of Coordinated Dinitrogen by Reaction with Dihydrogen and Primary Silanes

作者：Michael D. Fryzuk, Jason B. Love, Steven J. Rettig, Victor G. Young · 发表于：Science · 年份：1997 · DOI：10.1126/science.275.5305.1445 · 被引用次数：411 · 研究领域：Coordination Chemistry and Organometallics、Organometallic Complex Synthesis and Catalysis、Synthesis and characterization of novel inorganic/organometallic compounds

The reaction of dihydrogen with a side-on bound dinitrogen complex of zirconium was investigated. Instead of a displacement of the dinitrogen moiety, which is the common mode of reactivity, a complex containing both a bridging hydride and a bridging hydrazido unit with a nitrogen-hydrogen bond was observed. This reaction was extended to primary silanes to produce a species that contained a nitrogen-silicon bond. In addition, an intermediate in the dihydrogen addition has been structurally characterized as having a bridging dihydrogen unit.