Crystal Engineering of Acentric Diamondoid Metal-Organic Coordination Networks

作者：Owen R. Evans, Ren‐Gen Xiong, Zhiyong Wang, George K. Wong, Wenbin Lin · 发表于：Angewandte Chemie International Edition · 年份：1999 · DOI：10.1002/(sici)1521-3773(19990215)38:4<536::aid-anie536>3.0.co;2-3 · 被引用次数：561 · 研究领域：Metal-Organic Frameworks: Synthesis and Applications、Nonlinear Optical Materials Research、Crystallography and molecular interactions

Acentric three-dimensional coordination polymers bis(isonicotinato)zinc (1) and bis(4-pyridylacrylato)cadmium⋅H2O (2) were synthesized under hydro(solvo)thermal conditions; they exhibit a threefold (see picture) and fivefold diamondoid structure, respectively. Both 1 and 2 are active for second harmonic generation and exhibit remarkable thermal stability.