Ultrafast Click Conjugation of Macromolecular Building Blocks at Ambient Temperature

作者：Andrew J. Inglis, Sebastian Sinnwell, Martina H. Stenzel, Christopher Barner‐Kowollik · 发表于：Angewandte Chemie International Edition · 年份：2009 · DOI：10.1002/anie.200805993 · 被引用次数：223 · 研究领域：Click Chemistry and Applications、Chemical Synthesis and Analysis、Advanced Polymer Synthesis and Characterization

Block copolymers in seconds: Catalyst-free, ambient-temperature click conjugation of individual polymer strands becomes possible using novel ATRP-derived cyclopentadienyl-capped polymers in an extremely rapid hetero-Diels-Alder cycloaddition with macromolecules equipped with electron-deficient dithioester end groups prepared by the RAFT process.