High Uptakes of CO2 and CH4 in Mesoporous Metal—Organic Frameworks MIL-100 and MIL-101

作者：Philip L. Llewellyn, Sandrine Bourrelly, Christian Serre, Alexandré Vimont, Marco Daturi, Lomig Hamon, Guy De Weireld, Jong‐San Chang, Do‐Young Hong, Young Kyu Hwang, Sung Hwa Jhung, Gérard Férey · 发表于：Langmuir · 年份：2008 · DOI：10.1021/la800227x · 被引用次数：1140 · 研究领域：Metal-Organic Frameworks: Synthesis and Applications、Covalent Organic Framework Applications、Enhanced Oil Recovery Techniques

Mesoporous MOFs MIL-100 and MIL-101 adsorb huge amounts of CO2 and CH4. Characterization was performed using both manometry and gravimetry in different laboratories for isotherms coupled with microcalorimetry and FTIR to specify the gas-solid interactions. In particular, the uptake of carbon dioxide in MIL-101 has been shown to occur with a record capacity of 40 mmol g(-1) or 390 cm3STP cm(-3) at 5 MPa and 303 K.