Electrochemistry of polyacetylene, (CH) x : electrochemical doping of (CH) x films to the metallic state

作者：P. J. Nigrey, Alan Graham MacDiarmid, Alan J. Heeger · 发表于：Journal of the Chemical Society Chemical Communications · 年份：1979 · DOI：10.1039/c39790000594 · 被引用次数：209 · 研究领域：Electrochemical Analysis and Applications、Advanced Chemical Sensor Technologies、Spectroscopy and Quantum Chemical Studies

When silvery films of the semiconducting polymer, cis-‘polyacetylene,’(CH)x, are used as the anode in the electrolysis of aqueous KI solutions or methylene chloride solutions of [Bun4N]+[ClO4]–, films of (CHIy)x and [CH(ClO4)y]x, respectively, are obtained which, for the compositions [CHI0·07]x and [CH(ClO4)0·0645]x have high conductivities characteristic of the metallic state.