Electrochemical transformation of malonate and alkylidenemalonates into 3-substituted cyclopropane-1,1,2,2-tetracarboxylates

作者：Michaïl N. Elinson, Sergey K. Feducovich, S. G. Bushuev, Alexander A. Zakharenkov, D. V. Pashchenko, G. I. Nikishin · 发表于：Mendeleev Communications · 年份：1998 · DOI：10.1070/mc1998v008n01abeh000893 · 被引用次数：41 · 研究领域：CO2 Reduction Techniques and Catalysts、Cyclopropane Reaction Mechanisms、Asymmetric Hydrogenation and Catalysis

Electrolysis of malonate and alkylidenemalonates in an undivided cell in methanol in the presence of sodium bromide or sodium iodide as mediators leads to substituted 1,1,2,2-cyclopropanetetracarboxylates in 80–95% substance and 60–75% current yield.