A novel two-dimensional structure containing the first antimony-substituted polyoxovandium clusters: [{Co(en) 2 } 2 Sb III 8 V IV 14 O 42 (H 2 O)]·6H 2 O

作者：Lijuan Zhang, Xiao‐Li Zhao, Ji‐Qing Xu, Tie‐Gang Wang · 发表于：Journal of the Chemical Society Dalton Transactions · 年份：2002 · DOI：10.1039/b206250j · 被引用次数：95 · 研究领域：Polyoxometalates: Synthesis and Applications、Metal-Organic Frameworks: Synthesis and Applications、Nanocluster Synthesis and Applications

The novel framework [{Co(en)2}2SbIII8VIV14O42(H2O)]·6H2O is composed of two-dimensional arrays of {SbIII8VIV14O42(H2O)} clusters interlinked via {Co(en)2} bridging groups; such antimony–vanadium clusters with antimony and vanadium in low oxidation states were previously unknown.