Pd(II)-Catalyzed Intermolecular 1,2-Diamination of Conjugated Dienes

作者：Gregory L. J. Bar, Guy C. Lloyd‐Jones, Kevin I. Booker‐Milburn · 发表于：Journal of the American Chemical Society · 年份：2005 · DOI：10.1021/ja051181d · 被引用次数：296 · 研究领域：Asymmetric Hydrogenation and Catalysis、Carbon dioxide utilization in catalysis、Catalytic C–H Functionalization Methods

A Pd(II) chloride precatalyst, in the presence of 1 equiv of benzoquinone, effects highly efficient, regioselective 1,2-diamination of 1,3-dienes using dialkyl ureas under mild conditions. There is no requirement for a large excess of diene.