Tuning the Properties at Heterobimetallic Core: Mixed-Ligand Bismuth−Rhodium Paddlewheel Carboxylates

作者：Evgeny V. Dikarev, Bo Li, Haitao Zhang · 发表于：Journal of the American Chemical Society · 年份：2006 · DOI：10.1021/ja058294h · 被引用次数：65 · 研究领域：Cyclopropane Reaction Mechanisms、Asymmetric Synthesis and Catalysis、Asymmetric Hydrogenation and Catalysis

Mixed-ligand heterometallic compounds [BiRh(O2CCF3)4-x(O2CR)x] (R = But, x = 2 (cis); R = Me, Bui, x = 1) have been obtained by gas-phase reactions of bismuth(II) trifluoroacetate with the corresponding rhodium(II) carboxylate. This synthetic approach was found to be very effective for tuning the properties and introduction of chiral ligands at a heterobimetallic core.